ManufacturingET.org
Engineering Technology
Adhesives and Coatings
5:36 pm | January 15, 2012

Author: ManufacturingET.org | Category: | Comments: None

LECTURE PRESENTATION

Reading Assignment (Note: Reading assignment from multiple chapters)

  • 34.1 Adhesive Bonding
  • 34.2 Mechanical Fastening
  • 34.3 Joining of Plastics
  • 34.4 Joining of Ceramics and Glass
  • 34.5 Joining of Composites
  • 35.4 Coatings
  • 35.5 Vaporized Metal Coatings

Outline

Inorganic Coatings

Converted Surfaces and Coatings

  • Metal on metal
  • Metal on plastics
  • Ceramic on ceramic
  • Ceramic on metal

Phosphate Conversion Coatings

  • Creates a phosphate layer on the surface
  • Requires part to be clean first
  • Provides a base for painting, oiling, or waxing surface
  • Reduces friction (e.g., for processing)

Oxide Coatings (blackening and blueing)

  • Immersion of parts in hot caustic soda and nitrite or nitrate solution

Anodizing

  • Used on Al, Mg, and Titanium
  • Creates a protective oxide coating

Chromate Coatings

  • Used on Aluminum, Zinc, Cadmium coated steel. Also used on Mg and Sn coated steel.
  • Provides a decorative appearance
  • Used as a base coat for paint
  • May contain a dye to color the converted coating

 

Zinc chromate – silver
Zinc dichromate – gold

Metallic Coatings

  • Electroplating
  • Electroless and Immersion Plating
  • Dipping
  • Metallizing
  • Diffusion Coatings

Electroplating

  • Provides attractive surface finish
  • Improves wear resistance
  • Increase thermal conductivity
  • Improve materials ability to be soldered
  • Build up worn areas

Electroless Plating

  • Metal is deposited by chemical means
  • Used to deposit nickel, gold, tin, copper, cobalt and zinc to
    • Copper, aluminum, steel and plastic

Dipping

  • Base metal is cleaned
  • Dipped in flux
  • Molten metal bath
  • Excess metal drips off

 

Metallizing

  • Wire Metallizing or flame spraying
  • Plasma-arc spraying
  • Vacuum metalizing
    • Vaporized coating material using tungsten filaments
    • Vaporized metal floats in the vacuum and deposits on rotating parts
    • Used to coat automotive trim, reflectors, hardware, jewelry, etc.
    • Deposits high purity metal

 Ceramic Coatings

  • Porcelain Enamels
    • Glasslike material bonded to base metal
    • Fired from 1-2000 deg. F.
    • Durable, scratch resistant, easy to clean, resists chemicals and heat
  • Glazes
    • Glasslike material applied to ceramic material
  • Refractory Ceramic Coatings
    • High heat resistance

Organic Coatings

Coating Components

Solids

  • Pigments – small particles added to influence color a
  • Additives – special properties (thikenters, flow agente, fungicides, etc.)
  • Resins – unite pigments and binders

Solvents

  • Carry the solids, evaporate, release volatiles into the air (VOC’s – harmful interactions)

Powder coating

  •     no solvents

These may used as:

  • primers
  • sealer
  • base coats
  • clear coats
  • top coats
  • etc.

Resins are most important component

Polymer resins (all paints, liquid and solid are either enamels or lacquers)

Enamels - form film thru evaporation, cross link (more popular than lacquers)

Lacquers - do not cross link
Fluidization of the solids

  • Solution fluidization
    • Each molecule is dissolved in solvent
  • Dispersion fluidizaiton
    • Clumps
  • Emulsion fluidization
    • Large clusters of resin molecules surrounded with an emulsifier

Broad categories

  • Solvent born
  • Water born coatings
  • High solid coatings (low VOC) coatings
    •  Extremely popular bc of reduced solvent emmisions
    • Alkyds, polyesters, epoxies, acrylics, silicons

Coating Sequences

Pretreatment and cleaning – critical to success.

  • chemical
  • ultrasonic
  • vapor degreasing
  • often more than one method necessary

Application

  • Proper method depends on:
  • Type of paint
  • Thickness of paint
  • Properties required
  • Size and number of finished parts
  • Transfer efficiency (waste)
  • Methods:
    • Conventional air spraying
    • Airless spraying
    • Air-assisted airless spraying
    • High volume, low pressure spraying HVLP, less than 10 psi
      • softer, more control spraying
    • Electrostatic spraying
      • charged particles attracted to part with opposite polarity
    • Good transfer efficiency
    • Electrocoating
      • dip method of electrically applying paint

Curing

  • Room temterature
  • Heat Crosslinking
    • used for coating too slow to cross link at room temp
  • Radiation Curing
    • cured in seconds with UV or other radiation source.

Powder Coating

  • Applied dry, most cross link to form continuous film
  • Fine, homogenous plastic particles with additives
  • Electrostatically charged.
  • Melt when heated, tough film results
  • More E friendly (green)
  • Little waste, powder recoverable
  • Epoxy, polyseter, acrylic, silicon, hybrids
  • Sub-systems
    • pre-treatment system
    • application system
    • booth with powder recovery system
    • oven
    • conveyor

Sequence

Mechanical cleaning
water brushing
abrasive blasting
grinding
vibratory processing
chemical cleaning
solution: alkaline, neutral, acid, or emulsion

application system
pneumatic spray, fluidized powder

spray booth
50% adheres, efficient recovery of overspray is important
Filter collects overspray

Curing
convection ovens
infrared ovens    – transmits infrared radiation directly to surface cure faster, but even distribution is difficult.

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